Structural Assignment of Monothiocarbonohydrazones by 1H NMR Spectroscopy

Article abstract of DOI:10.1002/mrc.1270220103

Analysis of the 1H NMR spectra of several monothiocarbonohydrazones, some of them synthesized for the first time, shows that they exist as two structural isomers.Whereas, in general, the derivatives of aromatic aldehydes conform to a linear structure, the aliphatic carbonyl derivatives conform to heterocyclic or linear structures, depending on the size of the substituent groups.This dual behaviour is explained in terms of extended conjugation and steric hindrance.