LONG-RANGE INTRAMOLECULAR FUNCTIONALIZATION BY ALKOXYL RADICALS; LONG-RANGE INTRAMOLECULAR DOUBLE FUNCTIONALIZATION OF RING C OF CHOLESTANE AND ANDROSTANE SKELETONS

DOI: 10.1016/S0040-4039(00)97994-2

Source and publish data:

Tetrahedron Letters p. 5921 - 5924 (1990)

Update date:2022-08-04

Topics:

Authors:

Orito, Kazuhiko

Ohto, Masaru

Sugawara, Naoto

Suginome, Hiroshi

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Article abstract of DOI:10.1016/S0040-4039(00)97994-2

A one-step double introduction of a carbon-carbon double bond and oxygen functions to ring C of 5α-steroid skeletons, based on a long-range intramolecular hydrogen abstraction by alkoxyl radicals generated from the esters of 5α-cholestan-3α-ol carrying a

Full text of DOI:10.1016/S0040-4039(00)97994-2

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