SYNTHESIS OF ESTERS BY RHODIUM(I) CATALYZED BORATE ESTER-BENZYLIC BROMIDE CARBONYLATION REACTIONS

DOI: 10.1016/S0040-4039(01)91168-2

Source and publish data:

Tetrahedron Letters p. 3791 - 3794 (1984)

Update date:2022-09-26

Topics:

Authors:

Woell, James B.

Alper, Howard

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Article abstract of DOI:10.1016/S0040-4039(01)91168-2

Benzylic halides react with trialkylborates and carbon monoxide, in the presence of 1,5-hexadienerhodium chloride dimer, to give esters in excellent yields.The reaction is applicable to the synthesis of primary, secondary and even tertiary esters.

Full text of DOI:10.1016/S0040-4039(01)91168-2

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