Dissociative Ligand Exchange in Organoplatinum(II) and -gold(III) Complexes Having a Nucleoside Ligand. Dynamic NMR as a Mechanistic Probe for Ligand Exchange Process

Article abstract of DOI:10.1246/cl.1988.367

Application of simple dynamic NMR technique to intermolecular ligand exchange reactions in dimethylchloro(guanosine)gold(III) and ⁺ reveals that both reactions proceed by a dissociative mechanism.