Tetrahedron Letters p. 4909 - 4912 (1998)
Update date:2022-07-30
Topics:
Lindsay Smith, John R.
Shul'pin, Georgiy B.
The dinuclear manganese complex [LMn(IV)(O)3Mn(IV)L](PF6)2, where L is 1,4,7-trimethyl-1,4,7-triazacyclononane. catalyses the oxygenation of alkane by peroxyacetic acid or by H2O2 in the presence of acetic acid to give alkanols, alkanones and alkyl hydroperoxides. The reactions can give large turnovers (up to 1350 after 1 h at 20°C) and can occur with a high degree of retention of stereochemistry at tertiary carbon atoms.
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