Direct conversion of a benzylic hydroxy group into a selenenyl group using the phenyl trimethylsilyl selenide-aluminum bromide combination

DOI: 10.1248/cpb.46.1311

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1311 - 1313 (1998)

Update date:2022-08-05

Topics:

Authors:

Abe, Hitoshi

Yamasaki, Akira

Harayama, Takashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.46.1311

A new reagent system, phenyl trimethylsilyl selenide-aluminum bromide, was developed for the direct conversion of various benzylic hydroxy groups into a selenenyl group. Treatment of cinnamyl alcohol with this reagent system yielded 3,4-dihydro-4-phenyl-2H-1-benzoselenin via a [3,3]-sigmatropic rearrangement of the intermediate cinnamyl phenyl selenide.

Full text of DOI:10.1248/cpb.46.1311

NII-Electronic Library Service

Products guided by the article

Product name:1-methoxy-2-<(phenylseleno)methyl>benzene

Cas No:42778-12-1

R&D Labs maybe for 42778-12-1

Shanghai Yudiao Chemistry Technology Co.,Ltd

Contact:0086-18964703211

Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
Tengzhou Runlong Fragrance Co., Ltd.

website:http://www.tzrunlong.com/

Contact:--

Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China

Relevant to this article

Reduction of five-membered α,β-unsaturated lactones and related compounds with the Ni²⁺/BH₄^- system

Doi:10.1248/cpb.39.1167
(1991)
Doi:10.1016/S0040-4039(01)95814-9
(1973)
One to Find Them All: A General Route to Ni(I)-Phenolate Species

Doi:10.1021/jacs.1c03763
(2021)
Capturing Unknown Substrates via in Situ Formation of Tightly Bound Bisubstrate Adducts: S-Adenosyl-vinthionine as a Functional Probe for AdoMet-Dependent Methyltransferases

Doi:10.1021/jacs.5b05950
(2016)
Doi:10.1021/jo00916a034
(1974)
Inhibition of the α-carbonic anhydrase from Vibrio cholerae with amides and sulfonamides incorporating imidazole moieties

Doi:10.1080/14756366.2017.1327522
(2017)

Article Doi