Chemical and Pharmaceutical Bulletin p. 1311 - 1313 (1998)
Update date:2022-08-05
Topics:
Abe, Hitoshi
Yamasaki, Akira
Harayama, Takashi
A new reagent system, phenyl trimethylsilyl selenide-aluminum bromide, was developed for the direct conversion of various benzylic hydroxy groups into a selenenyl group. Treatment of cinnamyl alcohol with this reagent system yielded 3,4-dihydro-4-phenyl-2H-1-benzoselenin via a [3,3]-sigmatropic rearrangement of the intermediate cinnamyl phenyl selenide.
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