Journal of Organic Chemistry p. 1341 - 1344 (1984)
Update date:2022-09-26
Topics:
Tsuji, Jiro
Sato, Koji
Okumoto, Hiroshi
Allyl alkyl carbonates undergo a smooth decarboxylation-carbonylation reaction to afford β,γ-unsaturated esters at 50 deg C under atmospheric or low pressure of carbon monoxide and neutral conditions in the presence of palladium-phosphine complexes as catalysts.The reaction offers a very good method for the preparation of β,γ-unsaturated esters from allylic alcohols.
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