Palladium-Catalyzed Decarboxylation-Carbonylation of Allylic Carbonates To Form β,γ-Unsaturated Esters

DOI: 10.1021/jo00182a005

Source and publish data:

Journal of Organic Chemistry p. 1341 - 1344 (1984)

Update date:2022-09-26

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Authors:

Tsuji, Jiro

Sato, Koji

Okumoto, Hiroshi

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Article abstract of DOI:10.1021/jo00182a005

Allyl alkyl carbonates undergo a smooth decarboxylation-carbonylation reaction to afford β,γ-unsaturated esters at 50 deg C under atmospheric or low pressure of carbon monoxide and neutral conditions in the presence of palladium-phosphine complexes as catalysts.The reaction offers a very good method for the preparation of β,γ-unsaturated esters from allylic alcohols.

Full text of DOI:10.1021/jo00182a005

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