Thermal C-H Activation Catalyzed by RhCl(CH2=CH2)(PMe3)2. Hydrogen Transfer from Cycloalkanes to Ethylene and Ethylene Insertion into Cycloalkanes

DOI: 10.1246/cl.1991.359

Source and publish data:

Chemistry Letters p. 359 - 362 (1991)

Update date:2022-08-05

Topics:

Authors:

Sakakura, Toshiyasu

Tanaka, Masato

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Article abstract of DOI:10.1246/cl.1991.359

Dehydrogenation of cycloalkanes to cycloalkenes is catalyzed by RhCl(CH2=CH2)(PMe3)2 under ethylene pressure at a high temperature over 170 deg C.Ethylene insertion into sp³ C-H bond of cycloalkanes occurs at 230 deg C to afford ethylcycloalkanes.

Full text of DOI:10.1246/cl.1991.359

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