Journal of the American Chemical Society p. 4567 - 4572 (1994)
Update date:2022-09-26
Topics: Nuclear magnetic resonance (NMR) spectroscopy binding affinity X-ray crystallography Fluorescence Spectroscopy Complexation Metal ions Saccharides
Deng, Gang
James, Tony D.
Shinkai, Seiji
A diboronic acid saccharide (covalent) receptor site and a crown metal ion (electrostatic) receptor site are succesfully coupled in an allosteric system.The binding of monosaccharides with 2b as intramolecular 1:1 complexes was monitored by circular dichroism (CD).Added calcium perchlorate reduces the binding of the 1:1 saccharide complexes as followed by a decrease in the CD activity.This is a novel allosteric system which mimics the action of the Na+/D-glucose cotransport protein in nature.
View MoreSuZhou Hua-Emy Chemical Import and Export Co., LTD.
Contact:+86-512-88804994; +86-512-88804550;
Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
Shandong Yuanli Science and Technology Co., Ltd.
Contact:86-0536-6777557
Address:Zhuliu Industiral Park,Changle County
website:http://www.konochem.com
Contact:86-29-86107037
Address:No.170 West Avenue,Xi’an 710082,China
Hubei Xiangxi Chemical Industry Co.,Ltd
Contact:+86-710-3454830
Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
website:http://www.ringchemicals.com/
Contact:+1-416-493-6870
Address:Toronto, Canada
Doi:10.1021/acs.orglett.5b00276
(2015)Doi:10.1016/S0040-4020(02)00526-4
(2002)Doi:10.1016/S0040-4039(00)70226-7
(1966)Doi:10.1016/j.bmcl.2013.02.116
(2013)Doi:10.1021/jo01038a011
(1963)Doi:10.1021/jo026411a
(2002)
