Acid-catalyzed reactions of camphene and α-fenchene epoxides

DOI: 10.1023/A:1020335019901

Source and publish data:

Russian Journal of Organic Chemistry p. 810 - 822 (2002)

Update date:2022-07-31

Topics:

Authors:

Yarovaya

Korchagina

Gatilov Gatilov

Barkhash

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Article abstract of DOI:10.1023/A:1020335019901

Isomerization of camphene and α-fenchene epoxides under homogeneous and heterogeneous conditions in media of various acidity was studied. The intermolecular reactions of these epoxy compounds with unsaturated aldehydes, allyl alcohol and methanol on askanite-bentonite clay yielded spiroacetals, and open-chain hydroxyethers and acetals. The results obtained are compared to those for reactions with the initial monoterpenes.

Full text of DOI:10.1023/A:1020335019901

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