Journal of Molecular Catalysis A: Chemical p. 381 - 388 (2017)
Update date:2022-08-05
Topics:
Webster-Gardiner, Michael S.
Piszel, Paige E.
Fu, Ross
McKeown, Bradley A.
Nielsen, Robert J.
Goddard, William A.
Gunnoe, T. Brent
A series of new rhodium (I) complexes supported by bidentate nitrogen-donor ligands with varying electronic and steric properties were synthesized in situ and evaluated for catalytic arene C–H/D activation. In trifluoroacetic acid (HTFA), these complexes are proposed to mediate H/D exchange of arene C–H/D bonds by an electrophilic aromatic substitution mechanism that involves Rh-mediated activation of HTFA (or DTFA). DFT calculations support the proposed pathway for the H/D exchange reactions.
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