Journal of Molecular Catalysis A: Chemical p. 381 - 388 (2017)
Update date:2022-08-05
Topics:
Webster-Gardiner, Michael S.
Piszel, Paige E.
Fu, Ross
McKeown, Bradley A.
Nielsen, Robert J.
Goddard, William A.
Gunnoe, T. Brent
A series of new rhodium (I) complexes supported by bidentate nitrogen-donor ligands with varying electronic and steric properties were synthesized in situ and evaluated for catalytic arene C–H/D activation. In trifluoroacetic acid (HTFA), these complexes are proposed to mediate H/D exchange of arene C–H/D bonds by an electrophilic aromatic substitution mechanism that involves Rh-mediated activation of HTFA (or DTFA). DFT calculations support the proposed pathway for the H/D exchange reactions.
View MoreXi'an caijing Opto-Electrical Science & Technology Co., LTD
Contact:+86-29-88294447
Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Hangzhou Hysen Pharma co.,Ltd.
website:http://www.hysenpharma.cn/
Contact:0086-571-88298791
Address:#701,Gudun Road Hangzhou
Yuan Shi(SuQian)Biotechnology Co.,Ltd
website:http://www.yuanshibio.com
Contact:+86-527-84226672
Address:jiangsu suqian
Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.
Contact:+86-15853188990
Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
Shandong LuZhou Amino Acid Co., Ltd
Contact:86-539-2218025
Address:yishui economic and technical development zone zhenxing south road
Doi:10.1021/jo00920a008
(1974)Doi:10.1081/SIM-120015083
(2002)Doi:10.1002/anie.201304225
(2013)Doi:10.1007/BF01185888
(1965)Doi:10.1021/ja0359299
(2003)Doi:10.1002/jhet.5570250632
(1988)