Tetrahedron p. 2453 - 2460 (1990)
Update date:2022-08-02
Topics:
Barluenga, Jose
Perez-Prieto, Julia
Asensio, Gregorio
Allyl alcohols react with primary aromatic amines and stoichiometric amounts of mercury(II) tetrafluoroborate to give mixtures of mono- and diallyl anilines. However, the use of the tandem aminomercuration-deoxymercuration promoted by catalytic mercury(II) tetrafluoroborate allows to perform regiospecifically the monoallylation reaction with very high yields. A mechanism is proposed to account for the observed results.
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