Bulletin of the Chemical Society of Japan p. 3873 - 3874 (1981)
Update date:2022-08-05
Topics:
Ando, Teiichi
Ishihara, Takashi
Yamashita, Akira
Matsumoto, Masahiro
The Hunsdiecker reaction of Ag (E)- and (Z)-2,2-dichloro-1-methoxy-3-methylcyclopropanecarboxylates with bromine in CCl4 at 0 and 77 deg C occurs with substantial inversion of configuration, suggesting that the 1-methoxycyclopropyl radical is configurationally less stable than the 1-fluorocyclopropyl or the 1-methoxyvinyl radical.
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