Tetrahedron p. 7373 - 7388 (1995)
Update date:2022-09-26
Topics:
Ho
Ho, Wai Ming
Wong
Wong, Henry N. C.
Navailles
Navailles, Laurence
Destrade
Destrade, Christian
Nguyen
Nguyen, Huu Tinh
Isaert
Isaert, Noel
D-(+)-Glucose was used as a starting material to prepare four potentially useful chiral liquid crystalline molecules 2, 3, 4 and 5 having multiple chiral centers in their rigid cores. It is clear that 2 indeed incorporates properties essential for ferroelectric liquid crystals, i.e., a chiral smectic C phase with an induced spontaneous polarization of about 23 nC/cm2. Compound 3, on the other hand, shows only a nematic phase, while 4 merely shows a sharp melting point and 5 is an oil.
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