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First example of long distance stereocontrolled synthesis in 1-aza-3,7-dioxabicyclo[3.3.0.]octane series

DOI: 10.1515/HC.2005.11.3-4.305

Source and publish data:

Heterocyclic Communications p. 305 - 310 (2005)

Update date:2022-08-02

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Authors:

Maiereanu, CarmenMaiereanu, Carmen

Darabantu, MirceaDarabantu, Mircea

Condamine, EricCondamine, Eric

Ple, GerardPle, Gerard

Ramondenc, YvanRamondenc, Yvan

Fazekas, MarijanaFazekas, Marijana

Pintea, MonicaPintea, Monica

Berghian, CameliaBerghian, Camelia

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Article abstract of DOI:10.1515/HC.2005.11.3-4.305

The diastereoselective synthesis of (1R*,1′S*,2S*, 2′R*,5S*,5′R*,8R*,8′S*)-bis-1, 4-{1-aza-5-methyl-8-(4-nitrophenyl)-3,7-dioxabicyclo[3.3.0]octane-2-yl}benzene is described as the first example of a long distance stereocontrolled synthesis of this type of structure. The thermodynamic control of the reaction together with complete NMR evidence to support the stereochemistry of this compound are discussed.

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Full text of DOI:10.1515/HC.2005.11.3-4.305

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Download Date | 5/30/15 9:15 AM  
Brought to you by | Purdue University Libraries  
Authenticated  
Download Date | 5/30/15 9:15 AM  
Brought to you by | Purdue University Libraries  
Authenticated  
Download Date | 5/30/15 9:15 AM  
Brought to you by | Purdue University Libraries  
Authenticated  
Download Date | 5/30/15 9:15 AM  
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Products guided by the article

Product name:7a-methyl-3c,5c-bis-(4-nitro-phenyl)-(7ar)-dihydro-oxazolo[3,4-c]oxazole

Cas No:52049-50-0

52049-50-0

R&D Labs maybe for 52049-50-0

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