
Tetrahedron Letters p. 3955 - 3958 (1981)
Update date:2022-09-26
Topics:
Zhang
Yemul
Kagan
Stern
Commereuc
Chauvin
Cyclodiop, a chiral diphosphine with an intact PP bond was prepared and used as a ligand in rhodium complexes. Asynunetric reduction of some prochiral olefins was observed. The nature of the rhodium complexes is discussed in the light of their P nmr spectra.
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