Tetrahedron Letters p. 4431 - 4434 (1985)
Update date:2022-08-04
Topics: Chemistry Ring Structure Experimental Heterocyclic Thiadiazoline Spiro
Huisgen, Rolf
Mloston, Grzegorz
Proebstl, Albert
Diazomethane adds to one of the two faces of the sterically hindered thiofenchone furnishing the title compound wich extrudes N2 at 46 deg C whith t1/2=22 min; the thiofenchone S-methylide is intercepted by dipolarophiles and acts as a base in reactions with methanol, thiophenol and acetic acid, in the latter case accompanied by skeletal rearrangement.
View MoreContact:86-791-86629460
Address:1-6F, 118 Xinzhou road, Nanchang, Jiangxi, China
Shandong Xinke Petrochemical Co., Ltd.
Contact:+86-546-7277016
Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
Contact:0833-5590788/5590338/5590055
Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Zhejiang Genebest Pharmaceutical Co.,Ltd.
Contact:0086-571-63532866
Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Shanghai Yudiao Chemistry Technology Co.,Ltd
Contact:0086-18964703211
Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Doi:10.1080/10426500307947
(2003)Doi:10.1021/jm00257a002
(1974)Doi:10.1021/jo00906a024
(1975)Doi:10.1021/ac60183a042
(1962)Doi:10.1080/00397911.2010.524064
(2012)Doi:10.1055/s-1986-31739
(1986)
