Conformational Effects in the Hydrolyses of Rigid Benzylic Epoxides: Implications for Diol Epoxides of Polycyclic Hydrocarbons

DOI: 10.1021/ja00371a029

Source and publish data:

Journal of the American Chemical Society p. 1972 - 1978 (1982)

Update date:2022-07-29

Topics:

Authors:

Sayer, J. M.

Yagi, H.

Silverton, J. V.

Friedman, S. L.

Whalen, D. L.

Jerina, D. M.

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Article abstract of DOI:10.1021/ja00371a029

The two conformationally rigid, diastereomeric 9,10-oxides derived from trans-1,2,3,4,4a,10a-hexahydrophenanthrene have been synthesized, and their relative stereochemistries have been verified by X-ray structure determination of the acetate of the bromoh

Full text of DOI:10.1021/ja00371a029

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