Journal of the Chemical Society, Dalton Transactions p. 907 - 914 (1989)
Update date:2022-08-04
Topics:
Dyson, David B.
Parish, R. V.
McAuliffe, Charles A.
Pritchard, Robin G.
Fields, Roy
Beagley, Brian
The interaction of secondary phosphines with a variety of gold(I) compounds has been studied.In the presence of bases or polar solvents, polymeric gold(I) phosphides <(Au(μ-PR2))n> are formed.When these are obtained in the absence of additional ligands they are soluble, presumably with ring structures.More usually, insoluble forms are found, presumably with chain structures.The probable formation of these materials from complexes of the type
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