[3 + 2] annulation of allylic silanes in acyclic stereocontrol: Total synthesis of (9S)-dihydroerythronolide A

Article abstract of DOI:10.1021/ja034865z

The [3 + 2] annulation reactions of allylic silanes can be utilized to achieve acyclic stereocontrol. This method was employed as a key step in an enantioselective total synthesis of (9S)-dihydroerythronolide A. The key annulation reaction served to estab