Tetrahedron p. 3299 - 3308 (1982)
Update date:2022-08-04
Topics:
Kaulen, Johannes
Schaefer, Hans-J.
Primary alcohols, α,ω-diols and secondary alcohols are easily transformed into carboxylic acids, dicarboxylic acids or ketones, respectively, by heterogeneous oxidation with nickel oxide hydroxide electrochemically regenerated at a nickel hydroxyde electrode.The results are discussed in comparison to those of the nickel peroxide and chromic acid oxidation.The oxidation rate decreases with increasing steric hindrance of the alcohol, thus allowing the selective oxidation of the 3-position in hydroxysteroids.
View MoreQuzhou Aokai Chemical Co., Ltd.
Contact:86-570-3032832
Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China
Hangzhou Ledun Technology Co.,Ltd.
Contact:86-571-18767088918
Address:No.6 street,XiaSha,Hangzhou,China.
Zhejiang Newfine Industry Co.,Ltd.
Contact:+86-573-82262042
Address:No.225,Dongqing Road, garoms@163.com
YingYing Pharmaceutical Co.,Ltd
Contact:86-18854126208
Address:55#, yingxiongshan road
Contact:0550-7041128 0550-7090578
Address:Wangdian Street,Xinjie Town
Doi:10.1007/s00044-019-02310-y
(2019)Doi:10.1021/jm00335a005
(1964)Doi:10.1016/S0040-4020(01)97380-6
(1974)Doi:10.1039/C3974000956b
(1974)Doi:10.1016/S0008-6215(00)84171-3
(1975)Doi:10.1016/S0022-328X(96)06713-7
(1997)
