Synthesis and electrosynthesis of bis-silylated cyclopentadienylniobium(V) cationic complexes. Their reactions and structural characterization

DOI: 10.1016/0022-328X(91)86098-B

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Journal of Organometallic Chemistry p. 155 - 164 (1991)

Update date:2022-08-02

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Authors:

Antinolo, Antonio

Fajardo, Mariano

Otero, Antonio

Mugnier, Yves

Nabaoui, Hassane

Mourad, Houssef

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Article abstract of DOI:10.1016/0022-328X(91)86098-B

Chemical oxidation of complexes Nb(η⁵-C5H4SiMe3)2X2, X = Cl (1), Br (2), I (3), with ferrocenium hexafluorophosphate in dichloromethane gives the cationic complexes 5-C5H4SiMe3)2X2>⁺ PF6^-, X = Cl (4), Br (5

Full text of DOI:10.1016/0022-328X(91)86098-B

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