Journal of Organometallic Chemistry p. 297 - 304 (1980)
Update date:2022-07-29
Topics:
Davidson, Iain M. T.
Ostah, Naaman A.
Seyferth, Dietmar
Duncan, Don P.
Pyrolysis of octamethyl-1,2-disilacyclobutane(I) has been shown to proceed by a unimolecular isomerisation involving a biradical which undergoes internal hydrogen-abstraction.Kinetic data were obtained for this pyrolysis and for that of the oxidation product of I, octamethyl-1,3-disila-2-oxacyclopentane(II).A few additional experiments indicated that intermediates with ?-bonds to silicon may be generated by photolyis of I.The energetics of these reactions were discussed.
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