Journal of Organometallic Chemistry p. 297 - 304 (1980)
Update date:2022-07-29
Topics:
Davidson, Iain M. T.
Ostah, Naaman A.
Seyferth, Dietmar
Duncan, Don P.
Pyrolysis of octamethyl-1,2-disilacyclobutane(I) has been shown to proceed by a unimolecular isomerisation involving a biradical which undergoes internal hydrogen-abstraction.Kinetic data were obtained for this pyrolysis and for that of the oxidation product of I, octamethyl-1,3-disila-2-oxacyclopentane(II).A few additional experiments indicated that intermediates with ?-bonds to silicon may be generated by photolyis of I.The energetics of these reactions were discussed.
View MoreWuhan Sunrise Pharmaceutical Technology Co., Ltd
Contact:+86-27-83314682
Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
website:http://www.mingchem.com/en/index
Contact:0519-85170101-802
Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
website:http://www.shengmaochem.com
Contact:86-27-82853423, 82819281
Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China
JIANGXI XINXIN CHEMICAL CO., LTD.
Contact:86-15957176628
Address:INDUSTRY ROAD 1, INDUSTRIAL PARK, HEKOU TOWN,YANSHAN COUNTY, JIANGXI PROVINCE, CHINA
Dongguan Albiya Energy Science and Technology Co.,Ltd
Contact:+86-769-22181286
Address:Huanan Industial Park, Dongguan,China
Doi:10.1016/0040-4020(75)85028-9
(1975)Doi:10.1016/0040-4020(75)80040-8
(1975)Doi:10.1016/S0020-1693(02)01352-X
(2003)Doi:10.1016/j.tet.2018.02.053
(2018)Doi:10.1021/jf00059a035
(1995)Doi:10.1002/jlcr.2590100414
(1974)
