PALLADIUM-ASSISTED CARBOHYDRATE REACTIONS I. SODIUM CYANOBOROHYDRIDE-PROMOTED ALLYLIC REARRANGEMENTS OF C-6 SUBSTITUTED PYRANOSIDE GLYCALS.

DOI: 10.1016/S0040-4039(00)86900-2

Source and publish data:

Tetrahedron Letters p. 599 - 602 (1982)

Update date:2022-08-05

Topics:

Authors:

Dunkerton, Lois V.

Brady, Kevin T.

Mohamed, Farhana

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Article abstract of DOI:10.1016/S0040-4039(00)86900-2

Methoxypalladation of C-6 substituted pyranoside glycals followed by addition of sodium cyanoborohydride gives allylic rearrangement products in good yield with excellent regio- and stereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)86900-2

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Product name:methyl 2,6-di-O-acetyl-3,4-dideoxy-α-DL-threo-hex-3-enopyranoside

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