Synthetic Communications p. 1617 - 1624 (1994)
Update date:2022-07-29
Topics: Hydrochloric acid Protecting group Primary Amine Versatile Functional group Chemical compound Aqueous Amino group Carbon atom Mild procedure Formamidine Hydrolytic removal
Toste
McNulty
Still
A mild, zinc chloride-promoted cleavage of N,N,-dimethyl-formamidine derivatives of primary amines to the free amines is described. Under slightly different hydrolytic conditions the corresponding N-formyl derivatives can be isolated.
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