Tetrahedron p. 2045 - 2078 (1981)
Update date:2022-08-04
Topics:
Fukuyama, Tohru
Nakatsuka, Shin-Ichi
Kishi, Yoshito
Two general methods, Method A and Method B in Scheme 19, to synthesize epidithiapiperazinediones, are described.A total synthesis of racemic and optically active gliotoxin (1) and of racemic dehydrogliotoxin (53) was achieved by using Method A, whereas a total synthesis of racemic hyalodendrin (52) was completed by using Method B.
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