Journal of Organometallic Chemistry p. 171 - 186 (1986)
Update date:2022-08-04
Topics:
Cambie, Richard C.
Rutledge, Peter S.
Tercel, Moana
Woodgate, Paul D.
A pentacarbonylcarbene chromium complex of the diterpenoid methyl O-methylpodocarpate has been prepared and its reactions with some alkynes have been studied with the aim of synthesising ring-C aromatic steroids.The use of diphenylacetylene resulted in cyclisation to give steroidal derivatives in moderate yield.
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