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Chemistry of the Podocarpaceae LXX. Synthesis and Cyclopentaannulation of a Diterpenoid Chromium Carbene Complex

DOI: 10.1016/0022-328X(86)80436-3

Source and publish data:

Journal of Organometallic Chemistry p. 171 - 186 (1986)

Update date:2022-08-04

Topics:

Authors:

Cambie, Richard C.Cambie, Richard C.

Rutledge, Peter S.Rutledge, Peter S.

Tercel, MoanaTercel, Moana

Woodgate, Paul D.Woodgate, Paul D.

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Article abstract of DOI:10.1016/0022-328X(86)80436-3

A pentacarbonylcarbene chromium complex of the diterpenoid methyl O-methylpodocarpate has been prepared and its reactions with some alkynes have been studied with the aim of synthesising ring-C aromatic steroids.The use of diphenylacetylene resulted in cyclisation to give steroidal derivatives in moderate yield.

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Full text of DOI:10.1016/0022-328X(86)80436-3

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