Synlett p. 887 - 888 (1997)
Update date:2022-08-05
Topics:
Shimizu, Isao
Fujita, Munetsugu
Nakajima, Takayuki
Sato, Tadashi
Reaction of trisubstituted cyclic olefins with NaN3 in the presence of Cu(OTf)2 upon irradiation under oxygen gave keto nitriles in good yields. 1,5-Dimethyl-1,5-cyclooctadiene and 1,5,9-trimethyl-1,5,9-cyclododecatriene were converted into the corresponding unsaturated keto nitriles.
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