Chemistry - A European Journal p. 1594 - 1601 (2007)
Update date:2022-08-05
Topics:
Ahmed, Moballigh
Buch, Cathleen
Routaboul, Lucie
Jackstell, Ralf
Klein, Holger
Spannenberg, Anke
Beller, Matthias
Starting from [{Rh(cod)Cl}2] and 1,3-dimesitylimidazole-2- ylidenes the novel [RhCl(cod)(carbene)] complexes 1-5 have been synthesized, characterized, and tested in the hydroaminomethylation of aromatic olefins. The influence of different ligands and reaction parameters on the catalytic activity was investigated in detail applying 1,1-diphenylethylene and piperidine as a model system. The scope and limitations of the novel catalysts is shown in the preparation of 16 biologically active 1-amino-3,3-diarylpropenes. In general, high chemo- and regioselectivity as well as good yields of the desired products were achieved.
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