A CONVENIENT AND GENERAL SYNTHESIS OF 5-VINYLHEXOFURANOSIDES FROM 6-HALO-DEOXYPYRANOSIDES

DOI: 10.1016/S0040-4039(00)71373-6

Source and publish data:

Tetrahedron Letters p. 1213 - 1216 (1980)

Update date:2022-08-04

Topics:

Authors:

Nakane, Masami

Hutchinson, C. Richard

Gollman, Harold

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Article abstract of DOI:10.1016/S0040-4039(00)71373-6

The synthesis of five different 5,6-dideoxyhex-5-enofuranosides (5,7,9 and 11) proceeds in 30-60percent overall yield in two steps from commercially available 1-O-methyl pyranosides by reductive β-elimination of the intermediate 6-bromo-6-deoxypyranosides.

Full text of DOI:10.1016/S0040-4039(00)71373-6

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