The Use of Grignard Reagents in the Synthesis of Carbohydrates. III. The One-way Anomerization of Methyl Glycofuranosides and the Opening of Their Furanose Rings

DOI: 10.1246/bcsj.54.1492

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1492 - 1504 (1981)

Update date:2022-08-04

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Authors:

Kawana, Masajiro

Kuzuhara, Hiroyoshi

Emoto, Sakae

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Article abstract of DOI:10.1246/bcsj.54.1492

The anomerization of methyl glycofuranoside derivatives with methylmagnesium iodide or t-butylmagnesium bromide occurred in a one-way manner.For example, methyl 5-O-benzyl-β-D-ribofuranoside (3β) was converted into the corresponding α-anomer (3α) in a 95p

Full text of DOI:10.1246/bcsj.54.1492

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