The Use of Grignard Reagents in the Synthesis of Carbohydrates. III. The One-way Anomerization of Methyl Glycofuranosides and the Opening of Their Furanose Rings

DOI: 10.1246/bcsj.54.1492

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1492 - 1504 (1981)

Update date:2022-08-04

Topics:

Authors:

Kawana, Masajiro

Kuzuhara, Hiroyoshi

Emoto, Sakae

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.54.1492

The anomerization of methyl glycofuranoside derivatives with methylmagnesium iodide or t-butylmagnesium bromide occurred in a one-way manner.For example, methyl 5-O-benzyl-β-D-ribofuranoside (3β) was converted into the corresponding α-anomer (3α) in a 95p

Full text of DOI:10.1246/bcsj.54.1492

Products guided by the article

Product name:methyl 5,6-O-cyclohexylidene-3-deoxy-2-C-methyl-β-D-ribohexofuranoside

Cas No:58109-23-2

R&D Labs maybe for 58109-23-2

Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Jiangsu King Road New Materials Co., Ltd.

website:http://www.jskingroad.com

Contact:0519-85720726 0519-85720721 15006126856

Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
Hangzhou Hysen Pharma co.,Ltd.

website:http://www.hysenpharma.cn/

Contact:0086-571-88298791

Address:#701,Gudun Road Hangzhou
JIN TAN CHENG'EN CHEMICAL CO.,LTD.

Contact:86-519-82116250

Address:NO.102，village Dongfang，conomic development zone

Relevant to this article

Stereoselective preparation of N-[(R,R)-(E)-1-(3,4-dichlorobenzyl)-3-(2-oxoazepan-3-yl)carbamoyl]allyl- N-methyl-3,5-bis(trifluoromethyl)benzamide, a potent and orally active dual neurokinin NK₁/NK₂ receptor antagonist

Doi:10.1021/jm030786m
(2003)
Synthesis of poly (3,4,5-trihydroxybenzoate ester) dendrimers and their chemiluminescence

Doi:10.1016/S0040-4039(02)01959-7
(2002)
Reactions of some 2- and 4-O-triflylglycopyranosides with MeLi, t-BuOK, and pyridine

Doi:10.1016/S0008-6215(00)00291-3
(2001)
Doi:10.1021/jm00226a020
(1976)
An Improvment of the Anderson Test by the Use of High Performance Liquid Chromatography

Doi:10.1246/bcsj.61.606
(1988)
Doi:10.1021/jo00867a039
(1976)

Article Doi