
Chemistry of Natural Compounds p. 154 - 158 (1980)
Update date:2022-08-03
Topics:
Raldugin, V. A.
Salenko, V. L.
Gamov, N. S.
Titova, T. F.
Khan, V. A.
Pentegova, V. A.
From the oleoresin of the Yeddo spruce we have isolated a new sesquiterpene alcohol for which, on the basis of spectral and chemical chracteristics, the structure of 5S,8S-germacra-1E,6E-dien-5-ol (I) is suggested.The photocyclization of the alcohol isolated has given bourbonol, and its reaction with formic acid has yielded γ- and δ-cadinenes, the formates of T-muurolol and of T- and α-cadinols, and free T-muurolol and T- and α-cadinols
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