RADICAL MACROCYCLISATIONS IN SYNTHESIS. A NEW APPROACH TO MUKULOL AND MARINE CEMBRANOLIDE LACTONES

DOI: 10.1016/S0040-4039(00)95271-7

Source and publish data:

Tetrahedron Letters p. 621 - 624 (1989)

Update date:2022-08-05

Topics:

Authors:

Cox, Nicholas J. G.

Pattenden, Gerald

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Article abstract of DOI:10.1016/S0040-4039(00)95271-7

Radical macrocyclisations, involving the allylic dienones (11b) and (16), are shown to lead to 14-membered precursors, i.e. (12) and (18), for the synthesis of the marine cembranolide lactone (6) and mukulol (5) respectively.

Full text of DOI:10.1016/S0040-4039(00)95271-7

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