Journal of the Chemical Society, Dalton Transactions p. 1521 - 1528 (1990)
Update date:2022-08-04
Topics:
Burford, Neil
Royan, Bruce W.
Spence, Rupert E. v. H.
Cameron, T. Stanley
Linden, Anthony
Rogers, Robin D.
A number of adducts composed of phosphine oxides and Group 13 Lewis acids R3PO*EX3 (R = Ph, NMe2, or PhO; E = B, Al, or Ga; X = F, Cl, or Br) have been spectroscopically characterised by multinuclear n.m.r. spectroscopy.Three isostructural derivatives have been structurally characterised by X-ray crystallography.Crystal data (all hexagonal, space group <*>3, Z = 6): Ph3PO*AlCl3, a = 13.663(2), c = 18.258(2) Angstroem, R = 0.062; Ph3PO*AlBr3, a = 14.021(6), c = 18.387(3) Angstroem, R = 0.041; Ph3PO*GaCl3, a = 13.753(6), c = 18.345(6) Angstroem, R = 0.079.The structures show a uniquely linear or almost linear P-O-E backbone, which lies on the three-fold axis, in contrast to the bent structures observed for the corresponding BF3 adducts and other related systems.Short Al-O bonds
Anhui Sholon New Material Technology Co., Ltd.
website:http://www.sholonchem.com
Contact:+86-550-5261666
Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province
Laizhou City Laiyu Chemical CO.,Ltd
Contact:+86-535-2719337/2719339
Address:Chenggang road zhuyou laizhou City Shangdong China
Wuxi Forest Biological Co.,Ltd
Contact:+86-510-81602300
Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD
Contact:86-21-60560171
Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
website:http://www.greenutra.cn
Contact:0086-411-39553357
Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
Doi:10.1016/S0223-5234(03)00085-0
(2003)Doi:10.1021/jm00234a002
(1976)Doi:10.1021/ol005705k
(2000)Doi:10.1055/s-1981-29415
(1981)Doi:10.1021/jo01053a502
(1962)Doi:10.1055/s-1976-24024
(1976)
