Silenes in organic synthesis 1: Diastereoselectivity in the siloxysilene-diene Diels-Alder cycloaddition

DOI: 10.1016/0040-4039(96)00301-2

Source and publish data:

Tetrahedron Letters p. 2491 - 2494 (1996)

Update date:2022-08-04

Topics:

Authors:

Batsanov, Andrei S.

Clarkson, Ian M.

Howard, Judith A. K.

Steel, Patrick G.

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Article abstract of DOI:10.1016/0040-4039(96)00301-2

The siloxysilene (3) derived from thermolysis of benzoylpolysilane undergoes a facile in situ cycloaddition with a range of dienes to produce the corresponding cycloadducts with modest to good diastereoselectivity.

Full text of DOI:10.1016/0040-4039(96)00301-2

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