Tetrahedron p. 4607 - 4614 (1998)
Update date:2022-08-05
Topics:
Martinez, Antonio Garcia
Vilar, Enrique Teso
Fraile, Amelia Garcia
Fernandez, Antonio Herrera
De La Moya Cerero, Santiago
Jimenez, Florencio Moreno
The reaction of different substituted 2-norbomanones 1 with triflic anhydride in the presence of nitriles 6 is carried out in order to study the factors that influence on the different reaction possibilities of 2-norbomyl carbocations. The syntheses of interesting annulated pyrimidine derivatives 10 and conformationally rigid 1,3 disubstituted products are described.
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