Journal of Natural Products p. 1382 - 1383 (2003)
Update date:2022-08-04
Topics:
Armstrong, Veronica
Barrero, Alejandro F.
Alvarez-Manzaneda, Enrique J.
Cortes, Manuel
Sepulveda, Beatriz
An efficient and highly stereoselective synthesis of cytotoxic 8-epipuupehedione (1b) was achieved starting from natural (-)-drimenol (6). The key step to obtain stereoselectivity was the simultaneous demethylation and oxidation of the dihydrobenzopyran methoxy derivatives 10a and 10b.
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