Organic Letters p. 3550 - 3553 (2016)
Update date:2022-08-03
Topics:
Wang, Juan
Wang, Xiao-Hui
Liu, Xiao
Li, Jun
Shi, Xiao-Ping
Song, Yue-Lin
Zeng, Ke-Wu
Zhang, Le
Tu, Peng-Fei
Shi, She-Po
A curcuminoids, benzalacetone-, and quinolone-producing type III polyketide synthase (HsPKS3) from Huperzia serrata uniquely catalyzes the formation of unnatural 2-substituted quinolones and 1,3-diketones via head-to-head condensation of two completely different substrates. The broad range of substrate tolerance of HsPKS3 facilitates accessing structurally diverse 2-substituted quinolones and 1,3-diketones.
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