Synthesis p. 212 - 222 (1994)
Update date:2022-08-04
Topics:
Erker
Berlekamp
Lopez
Grehl
Schonecker
Krieg
Butadiene is 1,4-selectively coupled with a metal carbonyl and a ketone at the bis(η-cyclopentadienyl)zirconium template to yield the nine-membered metallacyclic products 3. Subsequent hydrolysis under oxidative conditions (pyridine N-oxide) gives the cor
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