HYDROCHLORINATION OF UNSATURATED COMPOUNDS BY THE ACTION OF CH2Cl2 OR CHCl3 AND RHODIUM COMPLEXES

DOI: 10.1007/BF00961299

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1213 - 1217 (1991)

Update date:2022-08-05

Topics:

Authors:

Khusnutdinov, R. I.

Shchadneva, N. A.

Dzhemilev, U. M.

Tolstikov, G. A.

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Article abstract of DOI:10.1007/BF00961299

A new method has been developed for the catalytic hydrochlorination of olefins and acetylenes in the presence of Rh complexes by means of HCl generated in situ from CH2Cl2 and CHCl3 under the reaction conditions.The reaction was studied using the hydrochlorination of propylene, 1-hexene, 1-nonene, vinylcyclopropane, 1,1-dicyclopropylethylene, cyclohexene, cyclooctene, norbornene, and 1,5-cyclooctadiene as examples.

Full text of DOI:10.1007/BF00961299

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