HYDROCHLORINATION OF UNSATURATED COMPOUNDS BY THE ACTION OF CH2Cl2 OR CHCl3 AND RHODIUM COMPLEXES

DOI: 10.1007/BF00961299

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1213 - 1217 (1991)

Update date:2022-08-05

Topics:

Authors:

Khusnutdinov, R. I.

Shchadneva, N. A.

Dzhemilev, U. M.

Tolstikov, G. A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00961299

A new method has been developed for the catalytic hydrochlorination of olefins and acetylenes in the presence of Rh complexes by means of HCl generated in situ from CH2Cl2 and CHCl3 under the reaction conditions.The reaction was studied using the hydrochlorination of propylene, 1-hexene, 1-nonene, vinylcyclopropane, 1,1-dicyclopropylethylene, cyclohexene, cyclooctene, norbornene, and 1,5-cyclooctadiene as examples.

Full text of DOI:10.1007/BF00961299

Products guided by the article

Product name:1,1,3-trichloro-2-methyl-propane

Cas No:62108-65-0

R&D Labs maybe for 62108-65-0

Ceresking Ecology & Technology co.,ltd

Contact:86 22 66218397

Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.
Sichuan JieYao Co., Ltd.

Contact:+86-838-5655598

Address:Guanghan Nanfeng Industrial Zone
Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
jiangsu haian chemical co.,ltd.

Contact:86-513-15851283853

Address:No.99,Changjiang West Road,Haian County,Jiangsu Province,China

Relevant to this article

Peptide-based inhibitors of hepatitis C virus full-length NS3 (protease-helicase/NTPase): Model compounds towards small molecule inhibitors

Doi:10.1016/S0968-0896(03)00190-1
(2003)
An efficient direct activation method transferring diastereopure platinum complex of BIPHEP to highly efficient Lewis acid catalyst for enantioselective carbonyl-ene reaction

Doi:10.1016/j.molcata.2005.12.006
(2006)
A Novel 2-Phenyl-1,2,3-Triazole Derived Fluorescent Probe for Recyclable Detection of Al³⁺ in Aqueous Medium and Its Application

Doi:10.1134/S1068162020040214
(2020)
Diastereoselectivities in Reductions of α-Alkoxy Ketones Are Not Always Correlated to Chelation-Induced Rate Acceleration

Doi:10.1055/s-0037-1610381
(2019)
Oximes in the Isoxazolone, Pyrazolone, and 1,2,3-Triazolone Series: Experimental and Computational Investigation of Energies and Structures of E/Z Isomers of α-Oxo-Oximes in the Gas Phase and in Solution

Doi:10.1071/CH15095
(2015)
Structure-activity relationship of 6-methylidene penems bearing 6,5 bicyclic heterocycles as broad-spectrum β-lactamase inhibitors: Evidence for 1,4-thiazepine intermediates with C7 R stereochemistry by computational methods

Doi:10.1021/jm060021p
(2006)

Article Doi