Intramolecular Free Radical Functionalisation of the Methyl Group of 5'-Deoxyadenosine

DOI: 10.1039/P19810003065

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3065 - 3069 (1981)

Update date:2022-08-04

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Authors:

Gani, David

Johnson, Alan W.

Lappert, Michael F.

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Article abstract of DOI:10.1039/P19810003065

Formation (2 methods) of a free radical at the 8-position of 5'-deoxy-2',3'-O-isopropylideneadenosine causes cyclisation with the 5'-methyl group to give, in yields of up 80percent, 5'-deoxy-2',3'-O-isopropylidene-5',8-cycloadenosine, identical with the p

Full text of DOI:10.1039/P19810003065

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