Functionalized organolithium compounds: Generation via reductive lithiation and nucleophilic addition to N-phenethylimides. Access to functionalized dihydropyrrolo[2,1-a]isoquinolinones

DOI: 10.1016/S0040-4020(98)00745-5

Source and publish data:

Tetrahedron p. 12361 - 12378 (1998)

Update date:2022-08-03

Topics:

Authors:

Manteca, Izaskun

Etxarri, Begona

Ardeo, Ainhoa

Arrasate, Sonia

Osante, Inaki

Sotomayor, Nuria

Lete, Esther

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Article abstract of DOI:10.1016/S0040-4020(98)00745-5

A procedure for producing 1,4-dianion equivalents consists of reductive lithiation, induced by 4,4-di-tert-butylbiphenylide, of functionalized phenyl sulfides. Nucleophilic addition of 4-lithio-2-(trimelhylsilylmethyl)but-1- ene 1 and 2-(3-lithiopropyl)-2

Full text of DOI:10.1016/S0040-4020(98)00745-5

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