Inorganic Chemistry Communications p. 1051 - 1055 (2003)
Update date:2022-08-05
Topics:
Zhu, Long-Guan
Kitagawa, Susumu
Two novel complexes, [Cu2(Hsal)4(4,4′-bipyridine)(H2 O)2(DMF)2] (1) (H2sal=salicylic acid) and {([Cu(Hsal)2(4,4′-bipyridine)](H2O) (H2sal)}n (2), were synthesized by layered-solution method and structurally characterized. Geometries of copper atoms in both complexes exhibit square pyramidal. Complex 1 is a dimer and hydrogen bonds between water and DMF molecules extend the structure into 1D hydrogen bonding network. Complex 2 consists of two-dimensional square framework structure.
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