Journal of Fluorine Chemistry p. 113 - 117 (2017)
Update date:2022-09-26
Topics:
Ma, Jing-jing
Liu, Qi-ran
Lu, Guo-ping
Yi, Wen-bin
A practical sliver-catalyzed fluoroalkylation of aryl-, heteroaryl- and alkylthiols has been developed. The reaction has a good functional-group tolerance and excellent selectivity. A variety of stable and solid fluoroalkanesulfinates including di- and perfluoroalkanesulfinates can be employed. This methodology provides a straightforward and streamlined access to perfluoroalkylthiolated organic molecules. [Figure presented]
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