Inorganic Chemistry p. 104 - 106 (1965)
Update date:2022-08-03
Topics:
Lustig, Max
Difluorodiazine undergoes reaction with some sulfur oxides and sulfur and phosphorus fluorides and oxyfluorides. These reactions are characterized by fluorination or fluorination with oxygen elimination. The quantitative syntheses of difluoramidosulfuryl fluoride, FSO2NF2, and pentafluorosulfur difluoramine, SF5NF2, and a high yield preparation of sulfuryl bromide fluoride, FSO2Br, are given. The isomerization of trans-N2F2 was accomplished at a temperature lower than formerly described.
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Doi:10.1016/j.tetlet.2010.11.102
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(2003)
