Chemistry Letters p. 567 - 568 (1997)
Update date:2022-08-05
Topics:
Patz, Matthias
Kuwahara, Yoshihiro
Suenobu, Tomoyoshi
Fukuzumi, Shunichi
The oxidation of a dimeric N-benzyldihydronicotinamide with various oxidants such as quinones, triphenyl carbenium ions and a triplet exited tris(bipyridine) ruthenium(II) complex occurs via initial outer-sphere electron transfer followed by fast C-C bond cleavage and second electron transfer. The kinetic studies allow the determination of the oxidation potential of this compound.
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