Chemical Communications p. 1783 - 1784 (1996)
Update date:2022-08-04
Topics:
Suzuki, Hitomi
Nonoyama, Nobuaki
In the presence of ozone at -78°C, nitrogen dioxide selectively reacts rapidly with adamantane at the bridgehead position to give the corresponding nitration product, while in the presence of methanesulfonic acid at 0°C, dinitrogen pentoxide readily reacts with this hydrocarbon at the same position exclusively to afford the corresponding nitrooxylation product, the yields of both products being quite satisfactory.
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