ACETAL MIGRATION DURING GLYCOSYLATIONS CATALYZED BY MERCURIC CYANIDE: SYNTHESIS OF p-NITROPHENYL 6-O-β-D-GALACTOPYRANOSYL-β-D-GALACTOPYRANOSIDE

DOI: 10.1016/S0008-6215(00)87139-6

Source and publish data:

Carbohydrate Research p. 37 - 50 (1981)

Update date:2022-08-04

Topics: Synthesis Glycosylations

Authors:

Abbas, Saeed A.

Barlow, Joseph J.

Matta, Khushi L.

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Article abstract of DOI:10.1016/S0008-6215(00)87139-6

Isopropylidenation of p-nitrophenyl β-D-galactopyranoside under kinetic control afforded the 4,6-acetal (2).The structure of 2 was established by 1H- and 13C- n.m.r. spectroscopy, and confirmed by methylation, and hydrolysis to 2,3-di-O-methyl-D-galactose

Full text of DOI:10.1016/S0008-6215(00)87139-6

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