Tetrahedron p. 16205 - 16212 (1997)
Update date:2022-08-04
Topics:
Azzena, Ugo
Carta, Simonetta
Melloni, Giovanni
Sechi, Alessandra
We have investigated the reductive cleavage of arylalkyl methyl ethers with an excess of lithium metal and a catalytic amount of naphthalene. The reaction proceeds regioselectively in the presence of various substituents on the aromatic ring, allowing access to a wide array of arylalkyl lithium derivatives some of which are not easily accessible by conventional methods.
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