ADDITION OF CHLORODISILANES TO ACETYLENE CATALYZED BY TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0). A FACILE ROUTE TO (Z)-1,2-BIS(CHLOROSILYL)ETHENES

DOI: 10.1016/S0022-328X(00)84520-9

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Journal of Organometallic Chemistry p. 43 - 48 (1980)

Update date:2022-08-05

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Authors:

Matsumoto, Hideyuki

Matsubara, Ikuya

Kato, Takayuki

Shono, Koichi

Watanabe, Hamao

Nagai, Yoichiro

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Article abstract of DOI:10.1016/S0022-328X(00)84520-9

In the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0), chlorodisilanes of type MenSi2Cl6-n (n=2-5) add to acetylene to afford 1,2-bis(chlorosilyl)ethenes in reasonable yields.

Full text of DOI:10.1016/S0022-328X(00)84520-9

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